I have looked pretty extensively at the documentation and it looks like there is no easy way to sign in through these two services.
I see that you have LoginWithGameCenter and LoginWithGoogleAccount but they don't work as I would have anticipated.
I figured the LoginWithGameCenter method would pop up some sort of GameCenter login window for the game. Instead it looks like I already have to have the users GameCenter id.
It also looks like the LoginWithGoogleAccount method is a Google+ account rather then a Google Play account.
This is a bit frustrating considering these are the most prominent ways players of each platform typically login for games and there is no clear cut way to do this.
Sorry if I'm coming off rude, I really love the service! I'm just a bit disappointed that it seems as though no leaderboard solution has yet figured out a simple intuitive way to integrate these services into Unity.
Thanks so much in advance for any help given!
P.S. I have tried the open source GooglePlayServices plugin, which is really nice, but I found our build was experience too many issues with it, which is why we are seeking out PlayFab.